Spreading and Curing Behaviors of a Thermosetting Droplet-Silicone on a Heated Surface

Thermosetting materials are widely used as encapsulation in the electrical packaging to protect the core electronic components from external force, moisture, dust, and other factors. However, the spreading and curing behaviors of such kind of fluid on a heated surface have been rarely explored. In this study, we experimentally and numerically investigated the spreading and curing behaviors of the silicone(OE6550 A/B, which is widely used in the light-emitting diode packaging) droplet with diameter of ～2.2 mm on a heated surface with temperature ranging from 25 ℃ to 250 ℃. For the experiments, we established a setup with high-speed camera and heating unit to capture the fast spreading process of the silicone droplet on the heated surface. For the numerical simulation, we built a viscosity model of the silicone by using the Kiuna's model and combined the viscosity model with the Volume of Fluid(VOF) model by the User Defined Function(UDF) method. The results show that the surface temperature significantly affected the spreading behaviors of the silicone droplet since it determines the temperature and viscosity distribution inside the droplet. For surface temperature varied from 25 ℃ to 250 ℃, the final contact radius changed from ～2.95 mm to ～1.78 mm and the total spreading time changed from ～511 s to ～0.15 s. By further analyzing the viscosity evolution of the droplet, we found that the decreasing of the total spreading time was caused by the decrease of the viscosity under high surface temperature at initial spreading stage, while the reduction of the final contact radius was caused by the curing of the precursor film. This study supplies a strategy to tuning the spreading and curing behavior of silicone by imposing high surface temperature, which is of great importance to the electronic packaging.     

全过程工程咨询下造价咨询企业现状与转型发展的机理、路径分析

全过程工程咨询背景下造价咨询企业转型发展依托于需求牵引和创新驱动,需要依托横向联盟战略及纵向整合战略.转型发展的路径可归纳为管理制度、创新理念、人才技术、业务整合、服务配套五个维度.研究结果可为造价咨询企业提供理论框架和实践指导,使其在转型发展过程中拥有更大竞争力.     

基于系统稳定性的燃煤发电机组综合对标评价方法研究与实践

对标管理方法在电力行业应用普遍，但传统火电机组对标方法由于指标覆盖面窄、数据利用不充分等原因而存在明显的局限性。对此，本文提出了燃煤发电机组稳定性对标评价的方法，确立了以过热蒸汽系统、再热蒸汽系统、冷端系统、烟风系统以及燃烧系统为主的系统集合，并用层次分析法根据各系统的特点进行了权重分配计算。筛选了各分系统的特征参数子集，根据重要程度进行了评级，最终形成燃煤机组综合对标评价体系。以某电力公司14台机组为例，计算了机组运行稳定性指标，对各机组的稳定性进行了评价，采用综合对标法进行排名。计算结果表明:本文所研究的综合对标法有着效率高、评价全面、结果清晰等特点，该方法在多台机组的应用中效果良好，有效地反映了各机组的稳定性运行情况，对提升燃煤机组生产管理水平起到了积极作用。     

透明阻燃PMMA复合材料性能研究

本篇文章研究甲基膦酸二甲酯、磷酸三(2-氯丙基)酯、三苯基磷酸酯三种磷系阻燃剂对PMMA性能的影响。通过本体聚合,分别制备了三种阻燃PMMA复合材料,以氧指数和垂直燃烧对阻燃性进行表征,通过耐热性、物理性能系统地研究了三种磷系阻燃剂对PMMA材料性能的影响。研究结果表明甲基膦酸二甲酯对PMMA阻燃性最优,30wt%DMMP/PMMA复合材料阻燃可达UL-94 V-0级别,但DMMP对PMMA有显著的增塑性,它引起复合材料的硬度、拉伸强度及维卡软化点大幅度下降。     

Gelling behavior of MgAl2O4 slurries with a common dispersant

MgAl₂O₄ transparent ceramics were shaped by a commonly used polyacrylic acid (PAA), which acted as both dispersant and gelling agent. The spinel slurries were prepared by ball-milling MgAl₂O₄ powder, PAA, and water in an attrition mill. The gelling of slurries happened at room temperature in air atmosphere without any other organic additive. The gelling mechanism was the formation of chelates between Mg²⁺ and carboxyl groups (-COO⁻) of PAA. The frequency-based testing method was applied to investigate the gelling process of the as-prepared slurry. In addition, a novel in situ characterization method based on a modified indentation testing was invented to better understand the strengthening of the wet green body with time and to guide when demolding could be carried out. After sintering, transparent MgAl₂O₄ ceramics with high in-line transmittance were resulted.     

Effects of Al doping on the electrochemical performances of LiNi0.83Co0.12Mn0.05O2 prepared by coprecipitation

The Ni-rich LiNi_0.83Co_0.12Mn_0.05O₂ (NCM83) cathode materials have drawn intensive attention due to the high energy density and low cost. However, Ni-rich LiNi_1-x-yCo_xMn_yO₂ still has the fatal weakness of poor cycle stability, limiting its further wide application. Bulk doping is an effective means to enhance the cycle stability, yet the electrochemical performances are very sensitive to the doping quantity. Here a facile method of co-precipitation is adopted to coat (Ni_0.4Co_0.2Mn_0.4)_1-xAl_x(OH)_2+x on precursor particles of NCM83. Al ions diffuse evenly in the NCM83 particles after sintering. The cells are operated at a high cut-off voltage of 4.5 V. The discharge capacity of NCM83 is 187.8 mAh g^?1, and decays fast with cycles. The doped sample even exhibits a higher discharge capacity of 195 mAh g^?1, and the capacity retention is improved to 83.8% after 200 cycles.     

刚柔结合的充电机械臂设计

针对大型运输设备上的电池充电补给任务,设计了一款刚柔结合充电机械臂.针对机械臂的柔性部分和刚性部分分别分析了关节、任务、驱动空间之间的运动映射关系,给出了两级柔性臂的解耦运动学算法,使用蒙特卡洛方法求解了机械臂的工作空间,验证了机械臂设计的合理性,并用Adams软件进行动力学仿真分析,校核了设备选型的安全性.